The equation 12HNO3 + 2As2S3 -> 2As2O5 + 12NO + 6H2O

  1. Detailed information about the equation 12HNO3 + 2As2S3 -> 2As2O5 + 12NO + 6H2O:

    • The chemical equation above describes the reaction of nitric oxidant (HNO3) with arsenic sulfide (As2S3).
    • According to the equation, each mol of As2S3 needs 6 mol of HNO3 to fully react and produce 1 mol of As2O5, 6 mol of NO and 3 mol of H2O.
    • This reaction is a redox reaction, in which As2S3 is oxidized to As2O5 and HNO3 is reduced to NO.
  2. Reaction conditions:

    • The reaction occurs at room temperature.
    • The reaction requires the presence of a strong oxidizing agent such as HNO3.
  3. Reaction process:

    • The reaction begins when As2S3 comes into contact with HNO3.
    • As2S3 is oxidized by HNO3, generating As2O5, NO and H2O.
    • The reaction continues until either As2S3 or HNO3 is exhausted.
  4. Occurring phenomena:

    • At the start of the reaction, a color change in the solution can be observed as As2S3 is oxidized.
    • The reaction produces NO gas, which is brown in color and is a toxic gas.
    • The formation of As2O5, a white solid, can also be observed.

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